ROLANDO
BARBUCCI
Curriculum
Vitae
Sede
di appartenenza:
Dipartimento
di Scienze e Tecnologie Chimiche e dei Biosistemi
Università
degli Studi di Siena
Via
Aldo Moro, 2
53100
Siena
phone
+ 39 0577 234382
fax
+ 39 0577 234383 / 234177
e-mail:
barbucci@unisi.it
Nato
a Firenze il 9 gennaio 1942
Qualifiche
Accademiche:
Laureato
in Chimica all'Università di Firenze nel 1965
Esperienza Professionale:
|
1967-1969 1970-1976 1976-1980 1980- 1990-1996 1991-1997 1992- 1996-2002 |
Professore Incaricato all'Università di Cagliari Professore Incaricato ed Assistenteall'Università di Firenze Professore ordinario all'Università di Napoli Professore ordinario all'Università di Siena (Facoltà di Farmacia) Direttore del Dipartimento di Chimica, Università di Siena Presidente del Gruppo Interdivisionale Biomateriali (G.I.B.) della Società Chimica Italiana Direttore del Centro Interuniversitario Sistemi Medici Avanzati (C.R.I.S.M.A.) Direttore
del Dipartimento di Scienze e Tecnologie Chimiche e dei Biosistemi |
Membro
di:
Società Chimica Italiana; Società Italiana dei Biomateriali; Gruppo di
Termodinamica dei Complessi; Royal Society of Chemistry (U.K.); Society for
Biomaterials (U.S.A.); Società Europea dei Biomateriali; New York Academy of
Science, American Association for the Advancement of Science.
Membro
dell'Editorial Board delle riviste: Biomaterials, Journal of Applied
Biomaterials & Biomechanics.
Membro dell’International Advisory Board dell’Academia Romana – Institute of Macromomolecular Chemistry “Petru Poni” (Romania) e del Biomahe – Centre of Excellence (Polonia).
Membro dell’Editorial Advisory Board della rivista “Recent Patents on Engineering”, Bebtham Science Publishers LTD.
Consulente
del Ministero dell'Università e della Ricerca Scientifica e Tecnologica per i
Piani Nazionali di Ricerca relativi ai Materiali Avanzati (Biomateriali).
Consulente
del Ministero delle Attività Produttive per i piani PIA.
Consulente
tecnico-scientifico
per la gestione del "Fondo speciale per la ricerca applicata"
dell'IMI.
Delegato
nazionale
per il Programma COST-Biomaterials della Comunità Europea dal 2002.
Coordinatore
dell’Azione COST 537 della Comunità Europea (2004-2009) dal titolo “Core
Laboratories for the Improvement of Medical Devices in Clinical Practice from
the Failure of the Explanted Prostheses Analysis (FEPA)” a cui partecipano 43
gruppi di ricerca provenienti da 17 paesi europei e 6 extraeuropei (Australia,
Cina, Giappone, Russia, Stati Uniti, Svizzera).
Coordinatore del Master di Secondo Livello in Biomateriali della Facoltà di Farmacia (settembre 2006-agosto 2007).
Promotore
di un gemellaggio fra le Università di Siena e di Kyoto (Giappone) che ha
portato dal 1990 al 2000 allo scambio di docenti e studenti fra le due Università,
in tutte le discipline rappresentate nei due Atenei, ed all’organizzazione di
convegni bilaterali interdisciplinari ogni due anni.
Promotore
e
Direttore
di un centro di ricerca di tecnologie biomediche (C.R.I.S.M.A.) dell'Università
di Siena diventato dal 1992 Centro Interuniversitario a cui partecipano le
Università di Siena, Bologna, Milano, Napoli e Bari.
Direttore
del
Corso Europeo Avanzato sui Biomateriali tenuto ogni due anni a Siena (aprile
1987; aprile 1989; aprile 1991, aprile 1993, aprile 1996, marzo 1998).
Direttore
del Sottoprogetto Biomateriali del C.N.R. nell'ambito del Progetto Finalizzato
Materiali Speciali per Tecnologie Avanzate 2 dal 1999.
Promotore
del Polo Universitario di Colle di Val d’Elsa (SI), Centro Didattico e di
Ricerca con l’istituzione di un Corso di Laurea in Chimica e Tecnologia dei
Materiali e Presidente del Comitato Tecnico-Scientifico.
Organizzatore di congressi internazionali: Biomaterials in Blood Therapy - European Research Coordination of Development, Testing and Applications (marzo 1985 - Siena); Workshop on Plasma Polymerization (ottobre 1990 - Siena); Siena - Kyoto Meeting (giugno 1991 - Siena; luglio 1995 - Siena); IV Macromolecules Metal Complexes (ottobre 1991 - Siena); International Congress on Biohydrogels (2007 – Viareggio).
Autore
di
250 pubblicazioni, brevetti ed Editore del libro “Integrated
Biomaterials Science” pubblicato da Kluwer Academic Publishers (2002).
E'
stato membro del Project Management
Group della Commissione delle Comunità Europee (Medical Research Program -
Euro. Biomat. Mat.).
E'
stato più volte valutatore dei
progetti europei sia per quanto riguarda il programma BIOMED che BRITE-EURAM
della Comunità Europea
Distinguished
Lecturer Award,
Symposium on Scientific Research on Priority Area of Macromolecular Complexes,
Japan, November 1988
Riconoscimento
conferito
dal Gruppo Interdivisionale Biomateriali della Società Chimica Italiana “per
l’alto contributo dato negli anni allo sviluppo della ricerca in Italia nel
campo dei biomateriali”, (1995).
MMC
Prize ricevuto
nell’ambito del 8th IUPAC Symposium per “distinguished contributions to the
Science of Macromolecules-Metal Complexes and for outstanding accomplishment in
ion complexes of biopolymers”, (1999).
PUBLICATIONS
1) R.Barbucci,
P.Paoletti, G.Ponticelli.
Complessi
del Cu(II) con amine tetradentale.
Proceedings X Congresso
S.C.I., Padova 17-21/6/1968, pp. 27.
2) R.Barbucci, G.Cialdi,
G.Ponticelli, P.Paoletti.
Infrared
and electronic spectra of isothiocyanate-and thiocyanato-polyamine
copper(II)
complexes.
J. Chem. Soc. (A), 1775-1777, 1969.
3) R.Barbucci,
P.Paoletti, A.Vacca.
Predictions
of enthalpies of protonation of amines. Log. K, H and S values
for
the protonation Ethylenediamine and Tri-tetra-, Penta-and Hexa-methylene
diamine.
J. Chem. Soc. (A), 2202, 1970.
4) R.Barbucci,
P.Paoletti.
Proprieta'
spettrali e stereochimica di alcuni complessi del Rame(II) con
leganti
amminici.
Proceedings C.N.R. Roma,
1970.
5) A.Vacca, A.Dei,
R.Barbucci, P.Paoletti.
Transition
metal complexes with substituent ethylene-diamines.
Proceedings XII I.C.C.C.,
Cracovia, Polonia, 14-22/9/1970, pp. 49-50.
6) P.Paoletti,
R.Barbucci, A.Vacca, A.Dei.
Thermodynamics
of protonation of amines-values of logK, H and S for the protonation of N'-and
NN-dimethyl ethylenediamine and NNN' N'-tetramethylethylenediamine.
J. Chem. Soc. (A), 1673, 1971.
7) R.Barbucci,
P.Paoletti, G.Ponticelli.
evidence
for coordination of thiocyanate and perchlorate groups in copper(II) complexes.
J. Chem. Soc. (A), 1637-1640, 1971.
8) P.Paoletti, R.
Barbucci, L.Fabbrizzi.
Progess
in thermodynamics of copper(II) polyamine complexes.
Proceedings of the meeting on "Stability and reactivity of the coordination compounds", Bressanone, 1971.
9) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Termodinamica
di formazione di addotti quadrati piramidali. Equilibri fra
complessi
poliamminici del rame ed alcuni anioni inorganici.
Proceedings of the IV Convegno A.I.C.I., Venezia 25-29/10/1971.
10) L.Fabbrizzi,
R.Barbucci, P.Paoletti.
Calori
ed entropie delle reazioni di alcune tetramine lineari alifatiche con
gli
ioni idrogeno, rame(II) e zinco(II).
Proceedings of the Convegno A.I.C.I., Venezia 1971.
11) P.Paoletti,
L.Fabbrizzi, R.Barbucci.
Termodinamica
di formazione di cationi pentacoordinati in
alcool metilico.
Proceedings
of the Meeting S.C.I. (Sez. Toscana),
Firenze 1972.
12) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Influenza
della grandezza degli anelli condensati sulla stabilità dei complessi del Ni(II),
Cu(II) e Zn(II) con triamine lineari alifatiche.
Proceedings
of the Meeting S.C.I. (Sez. Toscana),
Firenze 1972.
13) L.Fabbrizzi,
R.Barbucci, P.Paoletti.
Calori
di formazione ed energie di legame in alcuni complessi del Nichel(I).
Proceedings
of the Meeting S.C.I. (Sez. Toscana),
Firenze 1972.
14) R.Barbucci,
L.Fabbrizzi, P.Paoletti, A.Vacca.
Thermodynamics
of complex formation in aqueous solutions. Reactions of copper(II) with
ethylenediamine, NN'-dimethyl ethylenediamine, and
NN dimethylethylenediamine: logK, H and S values.
15) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Thermodinamics
of complex formation in aliphatic linear tetra-amines-
H and S for the reactions of 1,5,9,13 tetra-azatridecane with protons and sone
bivalent
transition metal ions.
J. Chem. Soc. Dalton, 740, 1972.
16) R.Barbucci, L.Fabbrizzi, P.Paoletti
Grandezza
degli anelli chelati e stabilità dei complessi metallici con tetramine lineari
alifatiche.
Proceedings
of the Meeting S.C.I. (Sez. Toscana),
Siena 15/6/1972, pp. 12-13.
17) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Funzioni
termodinamiche della neutralizzazione dello 1,3-diammino propano e della
formazione dell'acqua in soluzioni di differente concentrazione di KCl.
Proceedings
of the Meeting S.C.I. (Sez. Toscana),
Siena 15/6/1972, pp. 13-14.
18) R.Barbucci,
L.Fabbrizzi, P.Paoletti, A.Vacca.
Una
formula per valutare l'entalpia di protonazione delle ammine.
Proceedings
of the Meeting S.C.I. (Sez. Toscana),
Siena 1972.
19) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Formation
of five-coordinate cations between copper(II) polyamine complexes and some
inorganic anions. Standard thermodynamic
functions in methanol.
J. Chem. Dalton, 1099,
1972.
20) L.Fabbrizzi,
R.Barbucci, P.Paoletti.
Thermodynamics
of complex formation with linear aliphatic tetramines Part II heats and
entropies of the reaction of 3,7-diazanonane-1,9 diamine with hydrogen ions and
some bivalent transition-metal ions.
J. Chem. Soc. Dalton, 1529, 1972.
21) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Progress
in the thermodynamics of copper(II) polyamine complexes.
Coord. Chem. Rev., 8, 31, 1972.
22) R.Barbucci,
P.Paoletti, M.Campbell.
Studi
E.P.R. su complessi poliamminici del Cu2+ in soluzione.
Proceedings of the V Convegno A.I.C.I., Taormina 25-29/9/1972.
23) A.Vacca, R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Effetti
sterici sulla stabilità dei complessi del Ni2+ e Zn2+
in soluzioneacquosa. Reazioni con etilendiammine-N-metil sostituite.
Proceedings of the V Convegno A.I.C.I., Taormina 1972.
24) P.Paoletti,
R.Barbucci, L.Fabbrizzi, A.Vacca.
Termodinamica
dei complessi metallici con gli analoghi del trien(trietilentetrammina).
Procceding of the V Convegno A.I.C.I., Taormina 1972.
25) P.Paoletti,
R.Barbucci, A.Vacca.
Evaluation
of substituent effects on the enthalpies of protonation of amines. An empirical
formula of prediction.
J. Chem. Soc. Dalton, 2010, 1972.
26) L.Fabbrizzi,
R.Barbucci, P.Paoletti.
Grandezza
degli anelli condensati e funzioni termodinamiche dei complessi del Rame(II),
Nichel(II) e Zinco(II) con triamine lineari alifatiche.
Proceedings of the XI Convegno S.C.I., Perugia 1972.
27) R.Barbucci,
P.Paoletti, L.Fabbrizzi.
The
thermodynamic and electronic properties of some copper(II) five-co-ordinate
cations in non- aqueous solution.
J. Chem. Soc. Dalton, 2593-2596, 1972.
28) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Size
of the chelate rings and stability of some transition metal ion complexes
with
linear aliphatic triamines: 1,4,8, triazoctane (2,3,-tri).
Inorg. Chim. Acta, 7, 157, 1973.
29) R.Barbucci, A.Vacca.
Le
proprietà coordinanti dell'atomo di ossigeno in alcuni complessi con leganti
contenenti set di atomi donatori diversi.
Proceedings of the VI Convegno A.I.C.I., 24-29/9/1973, pp. 455-460.
30) P.Paoletti,
L.Fabbrizzi, R.Barbucci.
Enthalpies
de la protonation graduelle des bases polyaminiques dans les
solutions
aqueous.
Proceedings of the Conference de Thermodynamique Biologique, Marseille 1973.
31) R.Barbucci, L.Fabbrizzi, P.Paoletti.
Enthalpy
changes and colours of copper(II) tetramine complexes in solution and in solid
state.
Proceedings of the XV I.C.C.C., Moscow 1973.
32) P.Paoletti,
L.Fabbrizzi, R.Barbucci.
Chelating
properties of linear aliphatic tetramines with some bivalent transition metal
ions. 1,5,8,12-tetraazododecane
(3,2,3,)tet.
Inorg. Chem., 12,
1861, 1973.
33) P.Paoletti,
L.Fabbrizzi, R.Barbucci.
A
linear relationship between the enthalpy of formation and the frequency of
the
maximum in the electronic absorption spectra of the copper(II)-tetramine
complexes.
Inorg. Chem, 12,
1961, 1973.
34) R.Barbucci,
L.Fabbrizzi, P.Paoletti, A.Vacca.
Thermodynamics
of complex formation with linear aliphatic tetramines.
Part
III. Enthalpy and entropy contributions to the stability of metal complexes of
4,7-diazodecane-1,10 diamine.
J. Chem Dalton, 1763,
1973.
35) P.Paoletti,
L.Fabbrizzi, R.Barbucci.
Thermochemistry
of metal polyamine complexes.
Inorg. Chem. Acta Rev., 7, 43, 1973.
36) R.Barbucci,
P.Paoletti, M.J.M. Campbell.
E.s.r.
properties of some copper(II) polyamine complexes in non-aqueous
solvents.
Inorg. Chim. Acta, 10, 69, 1974.
37) R.Barbucci.
Differenze
ed analogie strutturali in alcuni complessi del Rame(II) con il legante
triaminico (2,4-tri) allo stato solido ed in soluzione acquosa.
Proceedings of the VII Convegno A.I.C.I., Pesaro 23-27/9/1974, .
38) R.Barbucci,
P.Paoletti.
The
donor properties of unsymmetrical linear aliphatic triamines towards some
transition metal ions in aqueous solution.
Proceedings of the XVI I.C.C.C., Dublin 1974.
39) A.Sabatini,
R.Barbucci, P.Paoletti, A.Vacca.
Titolazione
calorimetrica continua.
Proceedings of the
Convengo del G.T.C., Padova 1974.
40) R.Barbucci,
L.Fabbrizzi, P.Paoletti.
Thermodynamic
behaviour of complexes with 5,6-membered condensed chelate
rings: 1,4,8-triazaoctane.
J.
Chem. Soc. Dalton, 2403-2406, 1974.
41) R.Barbucci, A.Vacca.
Co-ordinating
properties in acqueous solution of the
oxygen atom in bis-2-aminoethyl ether.
J. Chem. Soc. Dalton, 2363-2367, 1974.
42) R.Barbucci.
A
thermodynamic investigation of the coordinating ability of N-(2-hydroxy ethyl)
ethylenediamine towards Copper(II) and Nickel(II) in aqueous solution.
Inorg. Chim. Acta. 12, 113, 1975.
43) R.Barbucci,
P.Paoletti, A.Vacca.
Stability
of some transition metal ion complexes with a linear aliphatic triamine
potentially forming a five membered chelate ring fused with a seven membered
chelate ring 1,4,9-triazanonane (2,4-tri)II.
Inorg. Chem. 14, 302, 1975.
44) R.Barbucci, M.J.M.Campbell.
Relazione
fra parametri e.p.r. e termodinamici nei complessi poliamminici del
Cu(II)
in soluzione acquosa.
Proceedings of the VIII Convegno A.I.C.I., Iesolo 1975.
45) R.Barbucci, M.J.M.Campbell.
EPR
spectra of trigonal bypyramidal copper(II) species Cu(R6tren)X+.
Inorg.
Chim. Acta, 15,
L15-L16, 1975.
46) R.Barbucci, M.J.M.Campbell.
An
investigation of the structures of copper(II) polyamine complexes in acqueous
solution by a combined evaluation of the EPR and thermodynamic
parameters.
Inorg.
Chim. Acta, 16,
113, 1976.
47) R.Barbucci,
L.Fabbrizzi, G.Noccioli.
Proprietà
termodinamiche e spettroscopiche di complessi del rame(II) con
spermidina
ed omologhi.
Proceedings of the
Convegno del G.T.C., Torino 1976.
48) R.Barbucci,
A.Bencini, D.Gatteschi.
Parametri
dell'Hamiltoniano di Spin per complessi di rame trigonali
bipiramidali.
Proceedings of the IX
Convegno A.I.C.I., Marina di Cantone 1976.
49) R.Barbucci,
G.Noccioli, M.J.M.Campbell.
Substituents
effects on the spectroscopic behaviour of a series of five
coordinate
copper(II) complexes.
Proceedings of the VII National Conference on Spectroscopy with Foreign Guests Participation, Slantchev Bryg (Bulgaria), 25-29/9/1976.
50) R.Barbucci, A.Budini.
Thermodynamic
electronic and electron paramagnetic resonance investigation of the coordinating
properties of 3-azoheptane-1,7-diamine in aqueous solution.
J. Chem. Soc. Dalton, 1321, 1976.
51) R.Barbucci.
Basicity
of free and coordinated aliphatic triamines.
Proceedings of the XVII I.C.C.C., Hamburg 1976.
52) R.Barbucci,
A.Mastroianni.
The
existence of large size chelate rings in metal(II) ion polyamine
complexes.
Proceedings of the XVIII I.C.C.C., Sao Paulo, 18-23/7/1977.
53) P.Paoletti,
R.Barbucci, L.Fabbrizzi (Editors).
Summer
School on Stability Constants.
Ed. Scuola Univ.
Firenze, 1977.
54) G.Arena, R.Cali,
E.Rizzarelli, S.Sammartano, R.Barbucci, M.J.M.Campbell.
Thermodynamic
and spectroscopic properties of mixed complexes in aqueous solution. Copper(II)
complexes of 2,2'-bipyridyl and cycloalkane 1,1-dicarboxylic acids.
J. Chem. Soc. Dalton, 581-585, 1977.
55) R.Barbucci,
A.Bencini, A.Gatteschi.
Electron
spin resonance spectra and Spin-Hamiltanion parameters trigonal-bypyramidal
Nickel(I) and Copper(II) complexes.
Inorg. Chem., 16,
2117-2120, 1977.
56) R.Barbucci.
Materie
prime per l'industria chimica.
Da "Enciclopedia
della Chimica", Ed.ISEDI, 4, 1977.
57) A.Anichini,
L.Fabbrizzi, R.Barbucci, A.Mastroianni.
Thermodynamic
and electron spin resonance spectroscopy investigation of the co-ordinating
properties of 4-azaoctane-1,8 diamine, (spermidine) in aqueous solution.
J. Chem. Soc. Dalton, 2224-2228, 1977.
58)
P.Paoletti, R.Barbucci.
Ossidoriduzione.
Ed. Sansoni Studio,
1978.
59) R.Barbucci,
A.Mastroianni, M.J.M.Campbell.
The
effect of N-alkylation on the properties of five coordinate copper(II) complexes
of tetra-amine ligands.
Inorg. Chim. Acta, 27, 109, 1978.
60) R.Barbucci
Studi
termodinamici e spettroscopici su polimeri multifunzionali idrosolubili,
con
struttura poliammido amminica.
Proceedings del Convegno
del Gruppo di Termodinamica dei Complessi,
Roma 5 giugno 1978.
61) R.Barbucci,
P.Ferruti.
Basicita'
e capacita' complessanti di polimeri multifunzionali
struttura poli(ammido-amminica).
Proceedings del Convegno
della S.C.I., Merano 18,23 giugno 1978.
62) R.Barbucci, V.Barone,
P.Ferruti.
Basicity
and copper(II) complex ability of multifuncional polymers with a poly(amido-amine)
structure.
Proceedings of the XIX I.C.C.C., Prague 4,8 september 1978.
63) V.Barone, R.Barbucci, P.Ferruti, M.Delfini, A.L.Segre, F.Conti.
Complex
formation of multifunctional polymers of a poly(amido-amine) structure and their
non macromolecular models with Copper(II) ion.
Proceedings of the
Convegno Nazionale di Chimica Inorganica,
Cosenza 23-29 settembre
1978.
64) G.Arena, R.Calì,
E.Rizzarelli, S.Sammartano, R.Barbucci, M.J.M.Campbell.
Thermodynamic
and spectroscopic properties of mixed complexes in aqueous solution. Copper(II)
complexes 2,2 bipyridyl and dicarboxylic acids.
J. Chem. Dalton,
1090-1094, 1978.
65) R.Barbucci,
P.Ferruti, C.Improta, M.Delfini, A.L.Segre, F.Conti.
Protonation
studies of multifunctional polymers with a
poly(amido-amine structure.
Polymer, 19, 1329-1334, 1978.
66) R.Barbucci.
Calorimetry.
Ed. Scuola Univ. di
Firenze, 1979.
67) R.Barbucci, V.Barone,
P.Ferruti.
Basicità
e capacità complessanti di poli(amido-amine) e loro modelli non macromolecolari
in soluzione acquosa.
Rendiconti Acc. Naz. dei
Lincei, LXIV, 5, 481, 1978.
68) R.Barbucci, V.Barone.
A
rationalization of the enthalpy of protonation of
polyamines.
J. Sol. Chem., 6, 427-438, 1979.
69) R.Barbucci,
C.Improta, L.Oliva, V.Barone, P.Ferruti.
Microcalorimetric
studies of the protonation in aqueous solution of regular polymers having a poly(amido-amine)
structure whose repeating units behave independently.
Proceedings of the 20th Microsymposium Microcalorimetry of Macromolecules, Prague 16-19 July 1979.
70) R.Barbucci, V.Barone, L.Oliva, P.Ferruti, T.Soldi, M.Pesavento, C.Riolo.
Macroinorganics.
Coordination compounds of polymeric ligands having a poly(amido-amine) structure
with heavy metal ions.
Proceedings of the International Symposium on Polymeric Amines and Ammonium Salts, Ghent 24-26 September 1979.
71) R.Barbucci,
P.Ferruti.
Protonation
and complex formation of some poly(amido-amine)s.
Polymer, 20, 1061-1062, 1979.
72) R.Barbucci, P.Ferruti, C.Impriota, M.La Torraca, L.Oliva, M.C.Tanzi.
Macroinorganics
IV-Thermodynamic functions relative to the protonation of a poly(amido-amine)
with repeating unit containing 3 amino groups.
Polymer, 20, 1298-1300, 1979.
73) R.Barbucci, P.Ferruti, M.Micheloni, M.Delfini, A.L.Segre, F.Conti.
Thermodynamic
and 13C n.m.r. data on the protonation of polymeric bases whose repeating units
behave independently towards protonation.
Polymer, 21, 81-85, 1979.
74) R.Barbucci, V.Barone, P.Ferruti, M.Delfini.
Macroinorganics
III. The chelation of Copper(II) ion with some polymers having a poly(amido-amine)
structure and their non macromolecular models.
J. Chem. Soc. Dalton, 253, 1980.
75) M.Delfini, A.L.Segre, F.Conti, R.Barbucci, V.Barone, P.Ferruti.
On
the mechanism of protonation of triamines.
J. Chem. Soc. Perkin II, 1980, 900-903, 1980.
76) R.Barbucci, V.Barone, L.Oliva, P.Ferruti, F.Soldi, M.Pesavento, C.Riolo.
Seven
membered chelate rings in Copper(II)complexes with spermidine.
Inorg. Chim. Acta, 46, 135-138, 1980.
77) R.Barbucci, V.Barone, L.Oliva, P.Ferruti, F.Soldi, M.Pesavento, C.Riolo.
Macro-Inorganics.
Coordination compounds with poly(amido-amine)s.
"(IUPAC)"-Polymeric amines and ammonium salts, Ed. E.J.Goethals, Pergamon
Press, Oxford, N.Y., 263-269, 1980.
78) P.Ferruti, L.Oliva, R.Barbucci, M.C.Tanzi
Macro
Inorganics V. Basicity and complexing ability of a new class of poly(amido-amines)
with tertiary amino groups present both in the main chain and as side
substituent.
Inorganica Chimica Acta,
41, 25-29, 1980.
79) R.Barbucci, V.
Barone, P.Ferruti, L.Oliva.
Thermodynamics
of protonation of polymeric bases whose repeating units behave independently.
J. Polymer Sci. Sym., 69, 49-66, 1981.
80) P.Ferruti, N.Danzo, L.Oliva, R.Barbucci, V.Barone.
Macroinorganics
VI. Protonation and complex formation of a new series of polymers whose
repeating units behave independently.
J.C.S. Dalton, 539-542,
1981.
81) R.Barbucci, V.Barone,
M.Micheloni, M.L.Rusconi.
Thermodynamics
of protonation of tetramines with different degrees of
N-methylation.
J. Phys. Chem., 85, 64-68, 1981.
82) V.Barone, R.Barbucci, N.Russo.
Intribsic basicities and structural modification in the step-wise protonation of aliphatic diamines.
Gazz. Chim. Ital., 111, 115-121, 1981.
83) R.Barbucci, M.Casolaro, P.Ferruti, V.Barone, F.Lelj, L.Oliva.
Macroinorganics
VII. Properties-structure relationship for polymeric bases whose monomeric units
behave independently towards protonation.
Macromolecules, 14, 1203-1209, 1981.
84) R.Barbucci, M.Casolaro, M.C.Beni, P.Ferruti, M.Pesavento, F.Soldi, C.Riolo.
Protonation
and complex complex formation with heavy-metal ions of two tetrafunctional
amines and of a new structurally related ion-exchange resin.
J.C.S. Dalton,
2559-2564, 1981.
85) P.Ferruti, R.Barbucci, N.Danzo, S.Pignataro, P.Torrisi, L.Puglisi, P.Spartano.
Preparation
and ESCA characterization of poly(vinylchloride) surface-grafted with heparin
complexing poly(amido-amine) chains.
Biomaterials, 3, 33-37, 1982.
86) R.Barbucci, P.Ferruti, V.Barone, M.Casolaro.
Macroinorganics
VIII. Chelation of Copper(II) ion with some new poly(amido-amine)s.
Polymer, 23, 148-151, 1982.
87) P.De Maria, A.Fini, P.Ferruti, M.C.Beni, R.Barbucci.
Catalysis
by polyelectrolytes whose monomeric units behave independently: effect of a poly(amido-amine)
on the ionization rate of ethyl nitroacetate.
Macromolecules, 15, 679, 1982.
88) P.Ferruti, C.Bertoglio Riolo, T.Soldi, M.Pesavento, R.Barbucci, M.C.Beni, M.Casolaro.
Applied
Macroinorganics II. Protonation and heavy metal ions complex-formation behaviour
of three cross-linked resins of poly(amido-amine) structure.
J. Applied Polymer Science, 27, 2239, 1982.
89) L.Rusconi, M.C.Tanzi, P.Ferruti, L.Angiolini, R.Barbucci, M.Casolaro.
Synthesis
of tertiary poly(amido-amine)s with amido- and amino- groups randomly arranged
along the macromolecular chain.
Polymer, 23, 1233-1236, 1982.
90) R.Barbucci, M.Casolaro, N.Danzo, M.C.Beni, V.Barone, P.Ferruti.
Thermodynamics
of protonation and complex formation of multifunctional polymers.
Gazz. Chim. Ital., 112, 105, 1982.
91) R.Barbucci, M.Casolaro, N.Danzo, V.Barone, P.Ferruti, A.Angeloni.
Effect
of different shielding groups on the polyelectrolyte behaviour of polyamines.
Macromolecules, 16, 456-462, 1983.
92) M.Flinterman, G.Challa, R.Barbucci, P.Ferruti.
Oxidative
coupling catalyzed by copper complexes of poly(amido-amine)s.
J. Mol. Catalysis, 18,
149, 1983.
93) P.Ferruti, I.Domini,
R.Barbucci, M.C.Beni, E.Dispensa, S.Sancasciani,
M.A.Marchisio,
M.C.Tanzi.
Heparin
adsorbing capacities at physiological pH of three poly(amido-amine) resins, and
of poly(amido-amine) surface grafted glass microspheres.
Biomaterials, 4,
218, 1983.
94) R.Barbucci,
M.Benvenuti, M.Pesavento, P.Ferruti.
Evaluation
of adsorbing capacity and selectivity of a new ion exchange resin with a poly(amido-amine)
structure.
Polymer, 24,
26, 1983.
95) R.Barbucci,
M.Casolaro, V.Barone, P.Ferruti, M. Tramontini.
Macroinorganics
9. Enthalpies of protonation and Cu(II) complex formation of some poly(amido-amine)s.
Macromolecules, 16, 1159-1164, 1983.
96) M.Pesavento, T.Soldi, P.Ferruti, R.Barbucci, M.Benvenuti.
Applied
Macroinorganics IV. Effect of the crosslinking agent on protonation, and metal
ions complexing abilities, of ion exchange resins with poly(amido-amine)
structure.
J. Appl. Pol. Sci., 28,
3361, 1983.
97) R.Barbucci,
M.Nocentini, A.M.Marabini.
Relationship
between the thermodynamic values of two poly(amido-amine)s and their dispersing
action on a copper mineral.
Colloids and Surfaces, 9, 205, 1984.
98) M.C.Tanzi, L.Rusconi,
C.Barozzi, P.Ferruti, L.Angiolini, M.Nocentini, V.Barone, R.Barbucci.
Synthesis
and characterization of piperazine-derived poly(amido-amine)s with different
distributions of amido-amine groups along the macromolecular chain.
Polymer, 25, 863, 1984.
99) P.Ferruti, R.Barbucci.
Linear
amino polymers: synthesis, protonation and complex formation.
Advances in Polymer Science, 58, 55, 1984.
100) R.Barbucci, M.Casolaro, P.Ferruti, M.C.Tanzi, L.Grassi, C.Barozzi.
Synthesis
and thermodynamic studies on the protonation behaviour of polymers containing
acylpiperazinyl units in the backbone or in the side chain of a vinyl polymer.
Makromol. Chem., 185, 1525-1535, 1984.
101) A.M.Marabini, M.Barbaro, R.Barbucci, M.Nocentini, S.Corezzi.
Mechanism
of action of new functionalized polymers in flocculation and dispersion of
chalcocite.
In Reagents in the Mineral Industry, 1984.
102) R.Barbucci,
P.Ferruti, G.Casini, F.Tempesti, R.Mastacchi, M.Sarret.
New
heparinizable materials III. Heparin retention power of a poly(amido-amine)
either as cross-linked resin or surface-grafted on PVC.
Biomaterials, 5,
234-236, 1984.
103) R.Barbucci, C.Bisi
Castellani, M.Delfini, P.Ferruti
Anticoagulative
surfaces: XPS study of polyamido-amine derivatives bonded to glass surface and
of their complexes with heparin.
Inorganica Chimica Acta,
93, L47-L48, 1984.
104) V.Barone, F.Lelj,
O.Nicolaus, G.Abbate, R.Barbucci
The mechanism of protonation of diamines in aqueous
solution. A
13C-NMR investigation.
Gazzetta Chimica
Italiana, 114, 249-251, 1984
105) R.Barbucci,
M.Benvenuti, G.Casini, P.Ferruti, F.Tempesti.
Surface
grafting of heparin-complexing poly(amido-amine) on poly(ethyleneterephtalate) (Dacron).
Makromol. Chem. Suppl., 9, 233-238, 1985
106) R.Barbucci,
M.Casolaro, S.Corezzi, M.Nocentini, P.Ferruti.
New
developments in macroinorganics - the thermodynamics of basic polymers.
Polymer, 26, 1353-1358, 1985.
107) P.Ferruti, M.A.Marchisio, R.Barbucci.
Synthesis,
physico-chemical properties and application of
poly(amido-amine)s.
Polymer, 26, 1336-1348, 1985.
108) R.Barbucci, G.Casini, P.Ferruti, F.Tempesti.
Surface-grafted
heparinizable materials.
Polymer, 26, 1349-1351, 1985.
109) R.Barbucci, M.Benvenuti, G.Casini, P.Ferruti, F.Tempesti.
Heparinizable
Materials IV. Surface-grafting on poly(ethyleneterephtalate) of heparin
complexing poly(amido-amine) chains.
Biomaterials, 6,
102-104, 1985.
110) R.Barbucci,
M.Benvenuti, G.Casini, P.Ferruti, M.Nocentini.
Heparinizable
Materials 5*. Preparation and FTIR characterization of polyurethane surfaces
grafted with heparin-complexing poly(amido-amine) chains.
Makromol. Chem., 186, 2291-2300, 1985.
111) R.Barbucci, M.Casolaro, M.Nocentini, S.Corezzi, P.Ferruti, V.Barone.
Acid-base
and metal ion complex formation properties of polymers containing amino acid
residues.
Macromolecules, 19, 37-42, 1986.
112) P.Ferruti, R.Barbucci, C.Barozzi, G.Casini, F.Tempesti.
Heparin
adsorbing resins of poly(amido-amine) structure and surface-grafting poly(amido-amine)s
on various materials.
In "Blood compatible and their testing", S.Dawids, A.Bantjes Editors, Martinus Nijhof Publishers, 187-192, 1986.
113) G.Casini,
M.Benvenuti, F.Tempesti, R.Barbucci, P.Ferruti.
Heparinizable
materials. preparation and properties of heparinized articles.
In "Blood compatible and their testing", S.Dawids, A.Bantjes Editors,
Martinus Nijhoff Publishers, Dordrecht, The Netherlands, pp. 193-200, 1986.
114) R.Barbucci,
M.Casolaro, P.Ferruti, M.Nocentini.
Spectroscopic
and calorimetric studies on the protonation of
polymeric aminoacids.
Macromolecules, 19, 1856-1861, 1986.
115) R.Barbucci, M.Casolaro, M.Nocentini, V.Barone, P.Ferruti.
Coordination
Chemistry of Metal Ions with Macromolecular Ligands.
In
"Metal Complexes in Solution", Edited by E.A.James, E.Rizzarelli and S.Sammartano, Piccini Ed. Padova (Italy),
133-153, 1986.
116) R.Barbucci, M.J.Campbell, M.Casolaro, M.Nocentini, G.Reginato, P.Ferruti.
Spectroscopic
and calorimetric studies of the complexing ability of some polyamido polymers
containing amino-acid residues.
J. Chem. Soc. Dalton Trans., 23-25, 1986.
117) R.Barbucci, M.Casolaro, M.Nocentini, G.Reginato, P.Ferruti.
Synthesis
and thermodynamic studies of two polymers carrying amido and amino groups in the
side chains.
Makromol. Chem., 187, 1953-1962, 1986.
118) R.Barbucci, M.Casolaro, S.Corezzi, G.Reginato.
Copper(II) complex properties of a basic polymer
containing SO2
groups in the main chain.
Polymer, 27, 19-86, 1986.
119) A.Fini, M.Casolaro, M.Nocentini, R.Barbucci, M.Laus.
Synthesis
and thermodynamic studies on protonation of a new polymeric amino acid.
Die Makromol. Chemie,
188, 1959, 1986.
120) R.Barbucci,
M.Benvenuti, G.Casini, P.Ferruti, F.Tempesti.
Heparin
immobilization on polyurethane surface; grafting of heparin complexing poly(amido-amine)s.
Polymers in Medicine II, Eds. E.Chiellini, P.Giusti, C.Migliaresi, L.Nicolais, Plenum Publishing Co 1986.
121) G.Azzuoli,
R.Barbucci, M.Benvenuti, P.Ferruti, M.Nocentini.
Chemical
and biological evaluation of heparinized poly(amido-amine) grafted polyurethane.
Biomaterials, 8,
61-66, 1987.
122) R.Barbucci,
M.Benvenuti, M.Casolaro, A.Billi.
Uptake
of metal ions from aqueous sulphuric acid by resins.
Polymer, 28, 969-976, 1987.
123) R.Barbucci, M.Benvenuti, G.Dal Maso, P.Ferruti, F.Tempesti, W.C.Lemm.
A
material (PUPA) presenting both the properties of polyurethanes and the capacity
of adsorbing high quantity of heparin.
Biomaterials, 9, 306-307, 1987.
124) R.Barbucci, A.Baszkin, M.Benvenuti, M.De Lourdes Costa, P.Ferruti.
Surface
characterization of heparin complexing poly(amido-amine) chains grafted on
polyurethane and glass surfaces.
Journal of Biomedical Materials Research, 21, 443-457, 1987.
125) R.Barbucci,
M.Benvenuti, P.Ferruti, M.Nocentini.
New
Heparinizable Materials: surface grafting of poly(amido-amine) chains on
polyurethane.
In "Advances in Biomedical Polymers", Ed. by C.G.Gebelein, Plenum Publ., 259-276, 1987.
126) R.Barbucci,
M.Casolaro.
Termodinamica
e spettroscopia I.R. di polimeri in soluzione
acquosa.
Da "Equilibri in
Soluzione, aspetti teorici sperimentali ed applicativi",
Marra Editore, 1988, pp
43-64.
126a) R.Barbucci,
M.Nocentini.
FTIR-ATR
characterization of a new biomaterial capable to adsorb high quantità of
heparin.
Mikrochim.
Acta, I, 279-282, 1988.
127) R.Barbucci,
M.Casolaro, M.Nocentini, P.Amodeo, G.Dal Maso, A.Fini.
Thermodynamic and spectroscopic studies on the
protonation and Cu+2 complex formation of a synthetic aminoacid:
(3-Amino propyl) malonic acid).
J. Chem. Soc. Dalton Trans., 1273, 1988.
128) R.Barbucci, M.Benvenuti, G.Dal Maso, P.Ferruti, M.Nocentini, R.Russo, F.Tempesti, R.Duncan, J.F.Bridjes, L.A.McCormick.
A
new material for biomedical application.
Polymers in Medicine III, Ed. by C.Migliaresi et al., Elsevier Sci. Publ. B.V., Amsterdam, 3-18, 1988.
129) R.Barbucci, M.Casolaro, A.Di Tommaso, A.Magnani.
Thermodynamic
and spectroscopic studies on the protonation of an optically active
polyampholite.
Macromolecules, 22, 3138-3143, 1989.
130) R.Barbucci, M.Casolaro, P.Ferruti, A.Magnani, C.Roncolini.
Vinyl
polymers containing amido and carboxylic groups as side substituents I.
Synthesis of N-acryloyl-glycine and N-acryloyl-6-caproic acid and their grafting
on cellular membrane.
Polymer, 30, 1715-1757, 1989.
131) R.Barbucci, M.Casolaro, A.Magnani.
Copper (II) complex formation with a poly(amido)
polymer containing optically active
-alanine residues.
Polymer Journal, 21
(11), 915-924, 1989.
132) R.Barbucci,
A.Magnani.
Physico-chemical
characterization and coating of polyurethane with a new heparin adsorbing
material.
Biomaterials, 10,
429-432, 1989.
133) R.Barbucci,
M.Benvenuti, G.Dal Maso,
M.Nocentini, F.Tempesti, M.Losi, R.Russo.
Synthesis
and physico-chemical characterization of a new material (PUPA) based on
polyurethane and poly(amido-amine) components, capable of strongly adsorbing
quantities of heparin.
Biomaterials, 10, 299-308, 1989.
134) R.Barbucci, M.Casolaro, A.Magnani.
Vinyl
polymers containing amido and carboxylic groups as side substituents II.
Thermodynamic and FT-IR spectroscopic studies for the protonation of poly(N-acryloyl-glycine)
and poly(N-acryloyl-6-caproic acid).
Die Makromolekulare
Chemie, 190, 2627-2638, 1989.
135) R.Barbucci,
F.Tempesti, A.Magnani.
Polyurethane
based materials for applications in bio-medicine.
First Mediterranean School of Science and Technology of Advanced Polymer
Based
Materials, Ed. by E.Martuscelli, G.Ragosta and C.Silvestre, 735-748, 1989.
136) R.Barbucci,
M.Casolaro, A.Fini.
The thermodynamics of protonation and copper(II)
complex formation of
-aminomalonic acid.
J.C.S. Dalton Trans.,
207-211, 1990.
137) M.Pesavento,
T.Soldi, C.Riolo, A.Profumo, R.Barbucci.
Sorption
of protons and heavy metal ions from aqueous solutions by three new resins
having a poly(amido-amine) structure.
Env. Protection Eng., 49,
16, 1990.
138) R.Barbucci et al.
Workshop
on the characterization of biomaterials in contact with blood.
Biomaterials, 11,
138-151, 1990.
139) M.Casolaro,
R.Barbucci.
Thermodynamic
of protonation and Cu(II)-complex formation with polyelectrolytes containing
different functional groups.
Second International Symposium on Polymer Electrolytes, Ed. by B.Scrosati,
Elsevier Applied Science, 311-324, 1990.
140) R.Barbucci,
M.Casolaro, A.Magnani, C.Roncolini.
FT-IR
and potentiometric study of basic polymer behaviour in the free form, in
different bulks, both in solid state and aqueous solution.
Polymer, 323 (5), 897-903, 1991.
141) R.Barbucci,
M.Casolaro, A.Magnani, C.Roncolini.
Different
protonation behaviour of two polymethacrylic acid derivatives containing
N-acyl-glycine and N-acyl-ß-alanine residues: thermodynamic and FT-IR studies.
Macromolecules, 24, 1249, 1991.
142) R.Barbucci,
A.Magnani, C.Roncolini.
Advantages
and problems using FT-IR spectroscopy to study blood-surface interactions by
monitoring the protein adsorption process.
In "Modern Aspects of Protein Adsorption on Biomaterials", Ed. by Y.F.Missirlis and W.G.Lemm, Kluwer Academic Publisher, The Netherlands, 91-96, 1991.
143) R.Barbucci,
A.Magnani, A.Albanese, F.Tempesti.
Heparinized
polyurethane surface through ionic bonding of
heparin.
ASAIO, 14
(8),499-507, 1991 .
144) R.Barbucci,
A.Magnani, C.Roncolini, S.Silvestri.
Antigene-antibody
recognition by Fourier Transform IR Spectroscopy/Attenuated Total Reflection
studies: biotin-avidin complex as an example.
Biopolymers, 31,
827-839, 1991.
145) R.Barbucci,
A.Albanese, A.Magnani, F. Tempesti.
Coating
of commercial available materials with a new heparinizable material.
J.
Biomed. Mater. Res., 25, 1259-1274, 1991
146) R.Barbucci, M.
Casolaro, A.Magnani.
The
role of polyelectrolytes in the permeability control of
insulin: behaviour of poly(N-acryloyl glycine) grafted on porous
cellulose membrane.
Journal of Controlled Release, 17, 79-88, 1991.
147) M.Casolaro,
R.Barbucci.
An
insulin releasing system responsive to glucose: thermodynamic evaluation of
permeability properties.
ASAIO, 14,
732-738, 1991.
148) R.Barbucci,
A.Magnani, C.Roncolini.
Thermodynamic
and FT-IR spectroscopic studies on heparin-polycation interaction.
Clinical Materials, 8,
17-23, 1991.
149) R.Barbucci,
A.Magnani
FT-IR
characterization of heparinizable polymer-coated materials for application in
biomedicine
Proceedings of 8th International Conference on Fourier Transform Spectroscopy, SPIE 1575, 461-462, 1991
150) R.Barbucci,
A.Magnani, F.Tempesti, M.Benvenuti.
Synthesis
of two novel heparinizable polymeric materials starting from an ethylene
vinylalcohol vinylacetate (EVALVA) terpolymer.
Die Makromolekulare
Chemie, 193 12, 2979-2988, 1992.
151) R.Barbucci,
F.Tempesti, M.Benvenuti, A.Magnani, A.Albanese.
Preparation,
physico-chemical and biological characterization of heparinizable materials.
In "Advances in Biomaterials: Biomaterial-Tissue Interfaces", P.J. Doherty, R.L.Williams, D.F.Williams, A.J.C.Lee (Eds.) Elsevier Vol. 10, p. 217, 1992.
152) R.Barbucci,
M.Casolaro, A.Magnani.
Characterization
of biomaterial surfaces: ATR/FT-IR and potentiometric/calorimetric analysis.
Clinical Materials, 11,
37-51, 1992.
153) R.Barbucci,
M.Casolaro, A.Magnani.
Ionic
and ionizable synthetic polymers: interactions in aqueous solution.
Coordination Chemistry Review, 120, 29-50, 1992.
154) M.Benvenuti,
R.Barbucci, E.Busi, A.Magnani.
Synthesis
of two novel heparinizable polymeric materials (EVAPA-45 and EVAPA) for
hemodialysis membranes.
In: "Omaggio
Scientifico a Renato Turriziani", Roma 1992.
155) R.Barbucci,
A.Magnani, A.Albanese, M.Benvenuti, M.Casolaro.
Biomaterials
and artificial organs.
In: "First Kyoto-Siena Symposium: The development of science for the improvement of human life", R.Barbucci, F.Casprini (Eds.), pp.19-37, 1992.
156) R.Barbucci,
A.Magnani
Surface
Infrared Analysis of Standard Biomaterials.
In: The References Materials of the European Communities: Results of Hemocompatibility Tests, W. Lemm (Ed.) Kluwer Academic Publisher, p.27, 1992.
157) R.Barbucci,
M.Benvenuti, A.Magnani, A.Albanese.
New
trends in blood compatible materials.
In: "Innovative Materials - Prospects and Problems in a Competitive Industrial Contest" Advances in Science and Technology 2, P.Vincenzini Ed., Techna Publishers 1993, pp. 537-574.
158) S.Cimmino, E.
Martuscelli, C.Silvestre,
R.Barbucci, A.Magnani, F.Tempesti.
Structure-property
relationships of polyurethane-based materials (PUPA) for application in
biomedicine.
Journal of Polymers Science, 47 (4), 631, 1993
159) M.Nocentini,
R.Barbucci.
Fourier
Transform Attenuated Total Reflection Infrared Spectroscopy (ATR/FT-IR).
In "Test Procedures for the Blood Compatibility of Biomaterials", S. Dawids (Ed.), Kluwer Academic Publishers (NL), 151-170, 1993.
160) A.Magnani,
R.Barbucci.
Fourier
Transform Attenuated Total Reflection Infrared Spectroscopy: application to
proteins adsorption studies.
In "Test Procedures for the Blood Compatibility of Biomaterials", S. Dawids (Ed.), Kluwer Academic Publishers (NL), 171-184, 1993.
161) R.Barbucci, A.Magnani, A.Baszkin, M.L.Da Costa, H.Bauser, G.Hellwig,
E.Martuscelli, S.Cimmino
Physico-chemical
surface characterization of hyaluronic acid derivatives as a new class of
biomaterials.
J. of Biomaterials Science, Polymer Edn., 4 (3), 245-273, 1993.
162) R.Barbucci,
M.Benvenuti, F.Tempesti.
New
perspectives in the hemocompatible polymeric materials.
In "Second Kyoto-Siena Symposium: The development of Science for the improvement of human life" - Y.Imanishi (Ed.) - Kyoto 1993, pp.23-34.
163) R.Barbucci,
M.Casolaro
Protonation
thermodynamics of membranes
grafted with polyelectrolytes controlling solute permeability.
Colloid and Surfaces A: Physicochemical and Engineering Aspects, 77, 81-89, 1993.
164) A.Albanese, R.Barbucci, J.Belleville, S.Bowry, R.Eloy, H.D.Lemke, L.Sabatini.
In
vitro biocompatibility evaluation of a heparinizable material (PUPA), based on
polyurethane and poly(amido-amine) components.
Biomaterials, 15 (2), 129-136, 1994.
165) R.Barbucci, E.Busi, A.Magnani, P.Ferruti, E.Ranucci, S.Taraviras.
Biomaterials.
La Chimica &
l'Industria, 1, 17-23, 1994.
166) R.Barbucci,
M.Benvenuti, F.Tempesti.
Modifications
to polymer surfaces to improve blood compatibility.
In "Polymeric Materials", Severian Dumitriu (Ed.), Marcel Dekker Publisher, 199-230, 1994.
167) R.Barbucci,
A.Magnani.
Conformation
of human plasma proteins at polymer surfaces: the effectiveness of surface
heparinisation.
Biomaterials, 15
(12), 955-962, 1994.
168) R.Barbucci,
M.Benvenuti, M.Casolaro, S.Lamponi, A.Magnani
Sulfated
hyaluronic acid as heparin-like material: physico-chemical and biological
characterisation.
J.
of Mater. Sci.: Mater. in Medicine, 5, 830-833, 1994
169) A.Magnani, E.Busi,
R.Barbucci
In
situ ATR/FTIR studies of protein adsorption on polymeric materials:
effectiveness of surface heparinisation.
J.
of Mater. Sci.: Mater. in Medicine, 5, 839-843, 1994.
170) R.Barbucci,
A.Albanese, F.Tempesti, A.Baszkin, R.Eloy,
N.Weill, E.Martuscelli, S.Cimmino
Study
of haemodyalisis materials: physico-chemical and biological characterisation of
EVALVA, EVAPA and heparinised EVAPA.
J.
of Mater. Sci.: Mater. in Medicine, 5, 844-849, 1994.
171)
R.Barbucci, S.Ciani
Siena
Group Experience
Materials Science and Engineering, A199, 65-68, 1995
172) R.Barbucci,
A.Magnani, M.Casolaro,
N.Marchettini, C.Rossi, M.Bosco.
Modification of hyaluronic acid by sulphate groups
insertion to obtain a heparin-like molecule. Part I. Characterisation and
behaviour in aqueous solution towards H+ and Cu2+
ions.
Gazzetta Chimica
Italiana, 125, 169-180, 1995
173) S.Lamponi,
F.Tempesti, A.Magnani, M.Benvenuti, R.Barbucci, E.Ranucci, S.Cimmino,
E.Martuscelli, A.Baszkin,
M.M.Boissonnade
Structural characterisation of a new heparinisable
material (EVAPA) based on ethylvinylalcohol vinyl acetate terpolymer (EVALVA)
and N2LL
polyamidoamine.
Macromolecular Chemistry and Physics, 196, 2123-2138, 1995.
174) R.Barbucci,
A.Magnani
A
challange to blood compatible materials in new materials perspectives.
In "Memorie di
Scienze Fisiche e Naturali", Serie V, Vol. XVIII, Parte II,
pp. 315, 1995
175) A.Magnani,
R.Barbucci, K.B.Lewis, D.Leach-Scampavia, B.D.Ratner.
Surface
properties and restructuring of a crosslinked polyurethane-poly(amido-amine)
network.
J. Mater. Chemistry, 5, 1321-1330, 1995
176) R.Barbucci,
A.Magnani.
Haemocompatible
Materials: Surface and Interface Aspects.
In "Ecyclopedia of Biomaterials and Bioengineering", Wise, Trantolo, Altobelli, Yaszemski, Gresser, Schwartz (eds.), Marcel Dekker Publisher, Vol. 2, pp. 1011-1041, 1995
177) R.Barbucci,
M.Casolaro.
Thermodynamic
of Stimuli-Responsive Polymers for Chemomechanical Membrane Systems.
In "Ecyclopedia of Biomaterials and Bioengineering", Wise, Trantolo, Altobelli, Yaszemski, Gresser, Schwartz (eds.), Marcel Dekker Publisher, Vol. 2, pp. 1385-1412, 1995
178) N.Nurdin, P.Francois, A.Magnani, N.Xanthopoulos, H.J.Mathieu, R.Barbucci, P.Vaudaux, P.Descouts
"Effect of toluene extraction on BiomerTM surface: I- ESCA, ATR/FTIR, contact angle analysis and biological properties"
J. Biomater. Sci. Polymer Edn., 7 (1), 49 (1995), Zeist - The Netherlands
179) R. Barbucci.
Polyions
for biocompatible materials.
Macromol. Chem. and Phys., 101, 413-422, 1996.
180) A. Magnani, A.
Albanese, S. Lamponi, R. Barbucci.
Blood-interaction
performance of differently sulphated hyaluronic acid.
Thrombosis Research, 81
(3), 383-395, 1996.
181) R. Barbucci, A.
Magnani, S. Lamponi, A. Albanese
Chemistry
and Biology of Glycosaminoglycans in blood coagulation
Polymer for Advanced Technologies, 7, 675-685, 1996
182)
R. Barbucci, A. Magnani, S. Lamponi, M. Casolaro
Different
sulphation degree and biological performance of hyaluronic acid as heparin-like
molecule.
Macromol. Symp., 105,
1-8, 1996
183) R. Barbucci,
S.Lamponi
Chemistry
and biology of glycosaminoglycans in blood coagulation
In "Third Kyoto-Siena Symposium: The development of Science for the improvement of human life" - R. Barbucci (ed.), Cadmo Publ., 73-96, 1996.
183a) R.Barbucci
Come migliorare
l’emocompatibilità di materiali destinati alla realizzazione di protesi
vascolari:possibili strategie.
NCF, 9, 56-57,
1996
184) G.Chen, Y.Ito, Y. Imanishi, A.Magnani, S.Lamponi, R.Barbucci
Photoimmobilization
of sulphated hyaluronic acid for antithrombogenicity.
Bioconjugate
Chemistry, 8, 730-734, 1997
185)
G. Abatangelo, R. Barbucci, P. Brun, S. Lamponi
Biocompatibility
and enzymatic degradation studies on sulfated hyaluronic acid derivatives.
Biomaterials, 18, 1411-1415, 1997
186) R. Barbucci
New
biocompatible material based on heparin-like molecules
In:
Proceedings of the "Fourth Kyoto-Siena Symposium: The development of
Science for the improvement of human life", Kyoto (Japan), 24/9-1/10/1997
187) R.Barbucci,
F.Zucchi.
Biomateriali
In "Manuale dei
materiali per l'ingegneria", McGraw-Hill Libri Italia, pp. 1011-1044, 1997.
188)
R. Barbucci, S. Lamponi, A. Magnani
Polimeri
per applicazioni cardiovascolari
In: Proceeding of F.A.S.T., November 1997.
189) R. Barbucci, F.
Venturi, A. Albanese.
Different
sulphation degree of hyaluronic acid as heparin-like molecule: physico-chemical
characterization and biological performance.
In: Frontiers in the Medical Application of Polymers, R.M. Ottembrite (Ed.), Technomic Publishing Co., Inc., Lancaster , PA – USA, pp. 157-170, 1998
190) M. Casolaro, R.
Barbucci
Thermodynamic behaviour of polyelectrolytes with the Lower Critical Solution Temperature phenomena.
In: Frontiers in the Medical Application of Polymers, R.M. Ottembrite (Ed.), Technomic Publishing Co., Inc., Lancaster , PA – USA, 7, 831-838, 1998
191)
R. Barbucci, A. Magnani, S. Lamponi, D. Renier
The
influence of molecular weight on the biological activity of sulphated hyaluronic
acid.
Biomaterials,
19, 801-806, 1998
192) A.Magnani,
S.Lamponi, R.Barbucci.
Complexes
of Copper (II) with glycosaminoglycans and their biological
activity
in: "Frontiers in the Medical Application of Polymers", R.M Ottenbrite (Ed.), Technomic Publishing Co., Inc., Lancaster , PA – USA, pp. 171-184, 1998
193) R. Barbucci
La
ricerca dei biomateriali: prospettive ed applicazioni
In "Conferenza
Annuale della Ricerca", Accademia dei Lincei, Atti dei Convegni Lincei, n.
137, 171-188, 1998.
194)
A.Magnani, S.Lamponi, R.Rappuoli, R.Barbucci
Sulphated
hyaluronic acids: a chemical and biological characterisation.
Polymer International, 46, 225-240, 1998
195) R. Barbucci, S. Lamponi, A. Magnani, L.F. Paoletti, N.P. Rhodes, M. Sobel, D.F.Williams
The
influence of sulfation on platelet aggregation and activation with differently
sulfated hyaluronic acids.
Journal of Thrombosis and Thrombolysis, 6, 109-115, 1998.
196) A.M. Aloisi, S.
Lamponi, I. Ceccarelli, R. Barbucci
Int. J. Art. Org., 21, 592-593, 1998.
197)
P.Favia, R.Palumbo, R.d'Agostino, S.Lamponi, A.Magnani, R.Barbucci
Immobilization
of heparin and highly-sulphated hyaluronic acid onto low-pressure
plasma-processed polyethylene
Plasmas and Polymers, 3, 77-96, 1998
198)
S.Lamponi, R.Barbucci, A.M.Aloisi
Effect
of behavioural stress on platelet reactivity on polymeric surfaces.
Journal
of Biomedical Material Research - Applied Biomaterials, 48,
9-12, 1999
199)
N. Marchettini, R. Barbucci, C. Bonechi, A. Donati, A. Magnani, V. Niccolucci,
E. Tiezzi
Structural study of hyaluronic acid oligomers and their complexes with copper in water by NMR and IR and molecular dynamics calculation
Macromolecular Symposia, 138, 203-208, 1999
Journal of Biomedical Material Research, 46, 186-192, 1999
201) R. Barbucci, A.
Magnani, S. Lamponi, M. Consumi
Biological
performance of two materials based on sulphated hyaluronic acid and polyurethane.
Journal of Materials Chemistry, 9, 2393, 1999
202) S. Lamponi, A.M.
Aloisi, R. Barbucci
The
role of Fbg in platelet adhesion to polymeric materials in conditions of
psychological stress.
Biomaterials, 19, 1791-1797, 1999
203) A. Magnani, V. Silvestri, R. Barbucci
Hyaluronic
acid and sulphated hyaruronic acid in aqueous solution: effect of the sulphation
in the polyelectrolyte behaviour and complex formation with Cu2+ and
Zn2+ ions.
Macromolecular Chemistry and Physics, 200, 2003-2014, 1999
204)
F. Cetta, R. Rappuoli, G. Montaldo, C. Baldi, M. Gori, D. Cetta, M. Zuckermann,
A. Magnani, R. Barbucci
New biliary endoprosthesis less liable to block in biliary infections: description and in vitro studies
Eur.
J. Surg., 165, 782-785, 1999
205) R. Barbucci, A.
Magnani, R. Rappuoli, S. Lamponi, M. Consumi
Immobilisation
of sulphatede hyaluronan for improved biocompatibility
Inorganic Biochemistry, 79,
119-152, 2000
206) R. Barbucci, A.
Magnani, S. Lamponi, R. Rappuoli, M. Consumi
Hyaluronan
derivatives: chemical modifications and biochemical applications.
In:
New Frontiers in Medical Sciences: Redifining Hyaluronan, Proceedings of the
Symposium held in Padova 17-19/6/1999, Eds. G. Abatangelo, P.H. Weigel, Elsevier
Publ., pp 203-212
207)
R. Barbucci, L. Ambrosio, A. Borzacchiello, R. Rappuoli
Synthesis
and chemical and rheological characterisation of new hyaluronic acid-based
hydrogels
Journal of Biomaterials Science – Polymer Edition, 11 (4), 383-399, 2000
208)
R. Barbucci, A. Magnani, S. Lamponi, S. Mitola, M. Ziche, L. Morbidelli, F.
Bussolino
Cu(II)
and Zn(II) complexes with hyaluronic acid and its sulphated derivative. Effect
on the motility of vascular endothelial cells.
Journal of Inorganic Biochemistry, 81(4), 229-237, 2000
209) R. Barbucci, A. Magnani
Metal-ion complexes in the angiogenetic effect
Macromolecular Symposia, 156, 239-251, 2000.
210)
A. Magnani, R. Barbucci, L. Montanaro, C.R. Arciola, S. Lamponi
In
vitro study of blood-contacting properties and effect on bacterial adhesion of a
polymeric surface with immobilizsed heparin and sulphated hyaluronic acid
Journal
of Biomedical Science. Polymer Edition, 11, 801-815, 2000
211)
A. Magnani, R. Rappuoli, S. Lamponi, R. Barbucci
212) R. Barbucci, A. Magnani, M. Consumi
The swelling
behaviour of the carboxymethylcellulose hydrogels in relation to crosslinking pH
and charge density
Macromolecules,
33 (20), 7475-7480, 2000
213) R. Barbucci, S.
Lamponi, A. Magnani, G. Peluso, O. Petillo
Metal
complexes with linear and crosslinked polysaccharides as mediators of
angiogenesis
Polymers for Advanced Technologies, 12, 271-278, 2001
214)
R. Barbucci, S. Lamponi, A. Magnani
Biological performance of materials
In:
Proceedings of Chemistry at the Beginning of the Third Millennium, Eds. L.
Fabbrizzi, A. Poggi, Springer Publ., Pavia
7-10 Oct. 1999, pp. 31-32.
215) R. Barbucci
Derivatized
hyaluronan for gels and nanochemically patterned surfaces
In: Hyaluronan 2000, Book of Abstracts, Ed. G.O. Phillips, Wrexam (UK) 3-8/9/2000, pp. 66-66.
216) A. Donati, A. Magnani, C. Bonechi, R. Barbucci, C. Rossi
Solution structure of
hyaluronic acid oligomers by experimental and theoretical NMR, and molecular
dynamics simulation
Biopolymers, 59, 434-445, 2001
217) S. Baccheschi, L. Sereni, C. De Nitti, R. Barbucci, C. Tetta
Blood tubings and
cytokine production: effect of sterilisation
Renal
Failure, 23 (3-4), 411-418, 2001
218) R. Barbucci, S. Lamponi, A.M. Aloisi
Platelet
adhesion to commercial and modified polymer materials in animals under
psychological stress and in a no-stress condition.
Biomaterials, 23, 1967-1973, 2002
219)
R. Barbucci, A. Magnani, G. Leone
The
effects of spacer arms in cross-linked hyaluronic hydrogel on Fbg and HSA
adsorption and conformation
Polymer, 43,
3541-3548, 2002
220)
R. Barbucci, M. Consumi, A. Magnani
Dependence
of water uptake and morphology of hyaluronan- and alginate-based hydrogels on pH
and degree of crosslinking.
Macromolecular
Chemistry and Physics, 203, 1292-1300, 2002
221)
R. Barbucci, G. Leone, A. Magnani, L. Montanaro, C.R. Arciola, G. Peluso, O.
Petillo
Cu2+
and Ag+-complexes with a hyaluronane-based hydrogel
Journal
of Materials Chemistry, 12, 3084-3092, 2002
222)
R. Barbucci, S. Lamponi, A. Borzacchiello, L. Ambrosio, M. Fini, P. Torricelli,
R. Giardino
Hyaluronic
acid hydrogel in the treatment of osteoarthritis
Biomaterials,
23, 4503-4513, 2002
223) R. Barbucci, D.
Pasqui, G. Leone
Derivatized
hyaluronan for gels and nanochemically patterned surfaces
In:
Hyaluronan - Chemical Biochemical and Biological Aspects, vol. 1, Eds. Kennedy,
Phillips, Williams and Hascall, Woodhead Publishing Ltd. (Cambridge, UK), 293-304, 2002
224)
R. Barbucci, S. Lamponi, A. Magnani, D. Pasqui
Micropatterned
surfaces for the control of endothelial cell behaviour
Biomolecular
Engineering, 19, 161-170, 2002
225)
R. Barbucci, A. Magnani,
S. Lamponi, D. Pasqui,
S. Bryan
The use of hyaluronan and its sulphated derivative patterned with micrometric scale on glass substrate in melanocyte cell behaviour
Biomaterials,
24, 915-926, 2003
226)
R. Barbucci, S. Lamponi, D. Pasqui, A. Rossi, E. Weber
Materials
Science and Engineering C, 23, 329-335, 2003
227)
A. Magnani, A. Priamo, D. Pasqui. R. Barbucci
Cell
behaviour on chemically microstructured surfaces
Materials
Science and Engineering C, 23, 315-328, 2003
228) S. Buttiglieri, D.
Pasqui, M. Migliori, H. Johnstone, S. Affrossmann. L. Sereni, R. Barbucci, C.
Tetta, G. Camussi
Endothelization
and adherence of leukocytes to nanostructured surfaces
Biomaterials,
24, 2731-2738, 2003
229)
D. Girotto, S. Rubani, P. Brun, D. Renier, R. Barbucci, G. Abatangelo
Tissue-specific
gene expression in chondrocytes grown on three-dimensional hyaluronic acid
scaffolds
Biomaterials,
24, 3265-3275, 2003
230)
R. Barbucci, D. Pasqui, A. Wirsen, S. Affrossman, A. Curtis, C. Tetta
Micro
and nano-structured surfaces
Journal
of Materials Science: Materials in Medicine, 14, 721-725, 2003
231)
R. Barbucci, S. Lamponi, A. Magnani
Fibrinogen
conformation and platelet reactivity in relation to material-blood interaction:
effect of stress hormones
Biomacromolecules,
4 (6), 1506-1513, 2003
Polysaccharides
based hydrogels for biological applications
Macromolecular Symposia, 204, 37-58, 2003
233)
R. Barbucci, G. Leone
Formation of defined microporous 3D-structures starting from cross-linked hydrogels
Journal
of Biomedical Materials Research (Applied Biomaterials), 68B, 117-126, 2004
234) G. Leone, A.
Borzacchiello, C. Migliaresi, L. Ambrosio, P.A. Netti, R. Barbucci
Preparation and physico-chemical characterisation of microporous polysaccharidic hydrogels
Journal
of Materials Science: Materials in Medicine, 15, 463-467, 2004
235)
E. Weber, A. Rossi, R. Gerli, S. Lamponi, A. Magnani, D. Pasqui, R. Barbucci
Micropatterned
hyaluronan surfaces promote lymphatic endothelial cell alignment and orient
their growth
Lymphology
37, 15-21, 2004
236)
R. Barbucci, G. Leone, A. Vecchiullo
Novel
carboxymethylcellulose-based microporous hydrogels suitable for drug delivery
Journal
of Biomaterials Science. Polymer Edition, 15(5), 607-619, 2004
237) D. Falconnet,
D. Pasqui, S. Parl, R. Eckert, H. Schift, J. Gobrecht, R. Barbucci, M. Textor.
A
novel approach to produce protein nanopatters by combining nanoimprint
lithography and molecular self-assembly
NanoLetters,
4(10), 1909-1914 2004
238) A. Magnani, R. Barbucci, S. Lamponi, D. Pasqui, A. Paffetti, L. Trabalzini, P. Martelli, A. Santucci
Two
step elution of human serum proteins from different glass modified bioactive
surfaces: a comparative proteomic analysis of adsorption patterns
Electrophoresis,
25, 2413-2424, 2004
239)
R. Barbucci, S. Lamponi, A. Magnani, F.M.
Piras, A. Rossi, E. Weber
Role
of the Hyal-Cu (II) complex on bovine aortic and lymphatic endothelial cells
behaviour on microstructured surfaces
Biomacromolecules,
6, 212-219, 2005
240) G. Giavaresi, P. Torricelli, P.M. Fornasari, R. Giardino, R. Barbucci, G. Leone
Blood
vessel formation after soft tissue
implantation of hyaluronan based hydrogel supplemented with copper ions
Biomaterials, 26, 3001-3008, 2005
241) R. Barbucci, A. Magnani, A. Chiumiento, D. Pasqui, I. Cangioli, S. Lamponi
Fibroblast
cell behavior on bound and adsorbed fibronectin onto hyaluronan or dulphated
hyaluronan substrates
Biomacromolecules,
6, 638-645, 2005
242) R. Barbucci. G. Leone, M. Monici, D. Pantalone, M. Fini, R. Giardino
The effect of amidic moieties on the polysaccharides: evaluation of the physico-chemical and biological properties of amidic carboxymethylcellulose (CMCA) in the form of linear polymer and hydrogel
Journal of Materials Chemistry, 15, 2234-2241, 2005
243) D. Pasqui, A. Rossi, R. Barbucci, S. Lamponi, R. Gerli, E. Weber
Hyaluronan and sulphated hyaluronan micropatterns: effect of chemical and topographic cues on lymphatic endothelial cell alignment and proliferation
Lymphology, 38, 50-65, 2005
244) T. Isoyama, D. Thwaites, M. G. Selzer, R. I. Carey, R. Barbucci, V. B. Lokeshwar
Differential selectivity of hyaluronidase inhibitors towards acidic and basic byaluronidases
Glycobiology 16(1), 11-21, 2006
245) R. Barbucci, P. Torricelli, M. Fini, D. Pasqui, P. Favia, E. Sardella, R. d’Agostino, R. Giardino
Proliferative and re-differentiative effects of photo-immobilised micro-patterned hyaluronan surfaces on chondrocyte cells
Biomaterials, 26, 7596-7605, 2005
246) D. Hamilton, M. Riehle, R. Rappuoli, W. Monaghan, R. Barbucci, A.S.G. Curtis
The response of primary articular chondrocytes to micrometric surface topography and sulphated hyaluronic acid-based matrices.
Cell Biology International, 29, 605-615, 2005
247) Rolando Barbucci, Milena Fini, Lucia Martini, Paola Torricelli, Roberto Giardino, Stefania Lamponi, Gemma Leone
Hyaluronic acid hydrogel added with ibuprofen-lysine for the local treatment of chondral lesions in the knee in vitro and in vivo investigations
Journal of Biomedical Materials Research: Part B – Applied Biomaterials, 75B, 42-48, 2005
248) R. Barbucci, G. Leone, S. Lamponi
The tixotropy property of hydrogels to evaluate the cell growing on the inside of the material bulk (Amber Effect)
Journal of Biomedical Materials Research, Part B, Applied Biomaterials, 76B, 33-40, 2006
249) Rolando Barbucci, Gemma Leone, Antonio Chiumiento, Maria Enrica Di Cocco, Giovanni D’Orazio, Raffaella Gianferri, Maurizio Delfini
Low and High resolution Nuclear Magnetic Resonance (NMR) characterisation of Hyaluronan based native and sulphated hydrogels
Carbohydrate Research, 341, 1848-1858, 2006
250) A. Chiumiento, A. Dominguez, A. Magnani, S. Lamponi, R. Villalonga, R. Barbucci
Anti-inflammatory properties of Superoxide Dismutase modified with Carboxymetil-cellulose polymer and hydrogel
Journal of Material Science, Materials in Medicine, 17(5), 424-435, 2006
EDITED
BOOKS
Integrated
Biomaterials Science
Edited
by R. Barbucci, Kluwer Academic/Plenum Publishers, New York (USA), 2002.
Microstructured
Biomaterial Surfaces
Proceedings
of the Symposium R, E-MRS Spring Meeting 2002, June 18-21, 2002, Strasbourg,
France. Edited by A.-C. Albertsson, R. Barbucci, A. Curtis, Special Issue of
Materials Science and Engineering C, Elsevier Science, Amsterdam-London-New
York-Oxford-Shannon-Tokyo, 2003
1) R.Barbucci, P.Ferruti, A.Grossi, W.G.Lemm.
Synthetic
material apt to stably adsorb highly quantities of heparin and
process
for the production thereof.
U.S. Patent n° 4,944,767 date of patent July 31, 1990.
2) R.Barbucci, G.Cialdi,
A.Magnani.
Novel
heparin-like sulfated polysaccharides
International Patent
Application, PCT Publication nr. WO 95/25751
3) L. Callegaro, R.
Barbucci, A. Magnani, M. Consumi
Acido
ialuronico solfatato e suoi derivati legati covalentemente a polimeri sintetici
per la preparazione di biomateriali e per il rivestimento di oggetti biomedicali
in campo sanitario e chirurgico.
Italian Patent n. PD
98A000037
4) R. Barbucci, R.
Rappuoli
Cross-linked Hyaluronic Acids and Medical uses thereof.
Italian Patent, nr. 1.303.735 (23.02.2001), priority: 11.11.1998
International
Application nr . PCT/EP99/08481.(8.11.1999
).
European
Patent : nr. EP 1144.459
( 02 10.2002)
US
Patent : granted in January 2004
5) R. Barbucci, G.
Sportoletti
Cross-linking Process of Carboxylated polysaccharides Italian
Italian
Patent : nr 1.303.738 (23.02.2001),
priority : 11.11.1998.
International
Application : nr PCT/EP99/08480.; PCT/……
US
Patent: granted in January 2004
6) R. Barbucci, A.
Magnani
Novel
heparin-like sulphated polysaccharides
EU Patent no.
99200468.9-2115
7) G. Cialdi, R.
Barbucci, A. Magnani
Sulfated
hyaluronic acid and esters thereof
US Patent n. 6,027,741, 22/02/2000
8) G. Cialdi, R.
Barbucci, A. Magnani
Sulfated
hyaluronic acid and esters
US Patent n. 6,051,701, 18/04/2000